===== Particle number expectation value ===== ==== Set ==== | @#55CCEE: context | @#55CCEE: $ w $ ... grand canonical weight | | @#FFBB00: definiendum | @#FFBB00: $ \langle\hat N\rangle(\beta,\mu) := \sum_{N=0}^\infty w_N(\beta,\mu)\cdot N $ | ----- === Discussion === The notation "$\langle\hat N\rangle$" is chosen for the function because we can also introduce the sequence of observables $\hat N$ defined to give us the particle number of each canonical ensemble, i.e. $\hat N_N=N$, and then the above coincides with the proper [[grand canonical expectation value]] of $\hat N$. Notice that this $\hat N$ is sometimes denoted by $N$, which can get a little confusing. === Theorems === * Given the [[grand potential]] $\Omega(\beta,\mu)$, we find ^ $ \langle\hat N\rangle = - \frac{\partial}{\partial\mu}\Omega $ ^ * For the deviation of the particle number, we find ^ $\frac{1}{\beta}\frac{\partial}{\partial\mu}\langle\hat N\rangle = \langle {\hat N}^2\rangle-\langle\hat N\rangle^2$ ^ * The entry [[grand canonical partition function]] shortly discusses free bosons and fermions. ----- === Context === [[Grand canonical weight]]