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classical_phase_density [2015/08/16 16:09] nikolaj |
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| === Volume in statistical physics === | === Volume in statistical physics === | ||
| - | A characteristic volume $V$ may be given by an integral over the spatial part of ${\mathcal M}$. This is e.g. how $V$ arises in the statistical mechanics derivation in the classical setting of the ideal gas law $p := -\frac{\partial}{\partial V}\langle{H}\rangle = \frac{N}{V}\cdot k_B T$. Introducing the density $n=\frac{N}{V}$, this holds true for infinite volumes. | + | A characteristic volume $V$ may be given by an integral over the spatial part of ${\mathcal M}$. This is e.g. how $V$ arises in the statistical mechanics derivation in the classical setting of the ideal gas law $p := -\frac{\partial}{\partial V}\langle{H}\rangle = \frac{N}{V}\cdot k_B T$. See also [[https://en.wikipedia.org/wiki/Cluster_expansion|Cluster expansion]]. |
| + | Introducing the density $n=\frac{N}{V}$, this holds true for infinite volumes. | ||
| In the derivation via quantum gases in an infinite volume, a volume parameter is introduced in when the momenta are quantized (see [[Classical density of states]]). | In the derivation via quantum gases in an infinite volume, a volume parameter is introduced in when the momenta are quantized (see [[Classical density of states]]). | ||
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| Wikipedia: | Wikipedia: | ||
| [[http://en.wikipedia.org/wiki/Continuity_equation|Continuity equation]], | [[http://en.wikipedia.org/wiki/Continuity_equation|Continuity equation]], | ||
| - | [[http://en.wikipedia.org/wiki/Liouville%27s_theorem_%28Hamiltonian%29|Liouville equations]] | + | [[http://en.wikipedia.org/wiki/Liouville%27s_theorem_%28Hamiltonian%29|Liouville equations]], |
| + | [[https://en.wikipedia.org/wiki/Cluster_expansion|Cluster expansion]] | ||
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