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Grand canonical expectation value

Set

context w … grand canonical weight
definiendum A:=N=0wNANN

The functional N denotes the expectation in the canonical ensamble of particle number N. So the grand canonical expectation value takes sequences of observables to a real.

Discussion

We adopt the names of observables in canonical ensamble for the grand canonical ensamble. For example, if the internal energy in the canonical ensamble is defined as U=H, then the grand canonical expectation value of the energy is denoted by U as well and if formed from the sequence of all the N-particle Hamiltonians HN.

We also extend functions f of classical canonical observables to such sequences. I.e. if A has AN, then f(A) has entries f(AN).

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