Grand canonical expectation value
Set
context | w … grand canonical weight |
definiendum | ⟨A⟩:=∑∞N=0wN⋅⟨AN⟩N |
The functional ⟨⋅⟩N denotes the expectation in the canonical ensamble of particle number N. So the grand canonical expectation value ⟨⋅⟩ takes sequences of observables to a real.
Discussion
We adopt the names of observables in canonical ensamble for the grand canonical ensamble. For example, if the internal energy in the canonical ensamble is defined as U=⟨H⟩, then the grand canonical expectation value of the energy is denoted by U as well and if formed from the sequence of all the N-particle Hamiltonians HN.
We also extend functions f of classical canonical observables to such sequences. I.e. if A has AN, then f(A) has entries f(AN).